王殳凹 教授博士生导师

 

邮箱：shuaowang@suda.edu.cn

通讯地址：苏州市工业园区仁爱路199号401号楼1305室

 

个人简历

王殳凹教授，放射医学与辐射防护国家重点实验室主任、苏州大学先进技术处处长、教育部CJ学者特聘教授、基金委杰出青年基金获得者。2007年在中国科学技术大学获理学学士学位，2012年在美国圣母大学获得博士学位，2012-2013年在美国劳伦斯伯克利国家实验室和加州大学伯克利分校开展博士后研究。多年来面向我国核能可持续发展和核安全重大战略需求，在核能放射化学领域取得了一批重要成果。他主持承担了科技部重点研发计划项目、基金委杰出青年基金项目、基金委重大仪器研制项目、GF科工局核能开发项目、JWKJW 163重点项目等科研项目，提出了放射性核素精准识别理念，并应用于乏燃料后处理、核污水处理、核事故应急等领域中，针对镧锕分离、含氚废水处理、铀骨骼促排等放射化学领域难题提供了科学依据和解决方案，并已初步在中核集团、中广核集团、军事科学院等单位实现应用，作为通讯作者在Nature (1篇，为该刊在乏燃料后处理超铀元素分离领域的首篇论文)、Nat. Commun. (8篇)、J. Am. Chem. Soc. (13篇)、Angew. Chem. Int. Ed. (15篇)、CCS Chem. (3篇)、Sci. China Chem. (5篇)、Chem (4篇)、ACS Cent. Sci. (1篇)等学术期刊发表论文172篇，全部论文被Science、Nature等期刊论文引用评价超过13500次，授权国际专利3项，中国专利21项，曾获中国青年五四奖章、中国青年科技奖等。

 

主要研究方向：

1. 核能放射化学

2. 环境放射化学

3. 辐射防护

4. 放射性元素化学

5. 辐射化学

6. 核技术应用

 

代表性论文：

(53) H. Zhang, A. Li, K. Li, Z. Wang, X. Xu, Y. Wang*, M. V. Sheridan, H.-S. Hu, C. Xu*, E. V. Alekseev, Z. Zhang, P. Yan, K. Cao, Z. Chai, T. E. Albrecht-Schönzart*, S. Wang*, “Ultrafiltration separation of Am(VI)-polyoxometalate from lanthanides” Nature, 2023, 616, 482-487.

(52) Y. Zhang, F. Li, Z. Cui, K. Li, J. Guan, L. Tian*, Y. Wang*, N. Liu, W. Wu, Z. Chai, S. Wang*, “A Radioluminescent Metal-Organic Framework for Monitoring 225Ac in Vivo” J. Am. Chem. Soc., 2023, in press.

(51) Y. Zhang, X. Wang, K. Xu, F. Zhai, J. Shu, Y. Tao, J. Wang, L. Jiang, L. Yang, Y. Wang, W. Liu*, J. Su*, Z. Chai, S. Wang*, “Near-Unity Energy Transfer from Uranyl to Europium in a Heterobimetallic Organic Framework with Record-Breaking Quantum Yield” J. Am. Chem. Soc., 2023, 145, 13161-13168.

(50) S. Mei, L. Chen, H. Zhang, Z. Li, L. Cheng, J. Lu, X. Li, Q. Yang, Y. Wang*, Z. Liu, Z. Chai, S. Wang*, “Assembling a Heterobimetallic Actinide Metal-Organic Framework by a Reaction-Induced Preorganization Strategy” Angew. Chem. Int. Ed., 2023, 62, e202306360.

(49) Y. Wang, M. Li, Z. Chai, Y. Wang*, S. Wang*, “Perovskite Scintillators for Improved X-ray Detection and Imaging” Angew. Chem. Int. Ed., 2023, 62, e202304638.

(48) C. Hu, L. Cheng, L. Zhou, Z. Jiang, P. Gan, S. Cao, Q. Li, C. Chen, Y. Wang, M. Mostafavi, S. Wang*, J. Ma*, “Radiolytic Water Splitting Sensitized by Nanoscale Metal-Organic Frameworks” J. Am. Chem. Soc., 2023, 145, 5578-5588. 

(47) J. Chen, M. Zhang, S. Zhang, K. Cao, X. Mao, M. Zhang, L. He, X. Dong, J. Shu, H. Dong, F. Zhai, R. Shen, M. Yuan, X. Zhao, G. Wu, Z. Chai, S. Wang*, “Metal-Organic Framework@Metal Oxide Heterostructures Induced by Electron-Beam Radiation” Angew. Chem. Int. Ed., 2022, 61, e202212532.

(46) B. Chen, J. Diwu, S. Wang*, “Perrhenate Recognition within a Superphane Cavity” Chem, 2022, 8, 1543-1545. 

(45) M. Li, Y. Wang, L. Yang, Z. Chai, Y. Wang*, S. Wang*. “Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X-ray Imaging” Angew. Chem. Int. Ed., 2022, 61, e202208440.

(44) X. Wang, F. Ma, S. Liu, L. Chen, S. Xiong, X. Dai, B. Tai, L. He, M. Yuan, P. Mi, S. Gong, G. Li, Y. Tao, J. Wan, L. Chen, X. Sun, Q. Tang, L. He, Z. Yang*, Z. Chai, S. Wang*, “Thermodynamics-Kinetics-Balanced Metal-Organic Framework for In-Depth Radon Removal under Ambient Conditions” J. Am. Chem. Soc., 2022, 144, 13634-13642. 

(43) B. Chen, S. Hong, X. Dai, X. Li, Q. Huang, T. Sun, D. Cao, H. Zhang, Z. Chai, J. Diwu*, S. Wang*, “In Vivo Uranium Decorporation by a Tailor-Made Hexadentate Ligand” J. Am. Chem. Soc., 2022, 144, 11054-11058.  

(42) Y. Bai, L. Chen, L. He, B. Li, L. Chen, F. Wu, L. Chen, M. Zhang, Z. Liu, Z. Chai, S. Wang*, “Precise Recognition of Palladium through Interlaminar Chelation in a Covalent Organic Framework” Chem, 2022, 8, 1442-1459. 

(41) C. Liang, L. Cheng, S. Zhang, S. Yang, W. Liu, J. Xie, M. Li*, Z. Chai, Y. Wang*, S. Wang*, “Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal-Organic Framework” J. Am. Chem. Soc., 2022, 144, 2189-2196. 

(40) H. Lu, J. Xie, X. Wang, Y. Wang, Z. Li, K. Diefenbach, Q. Pan*, Y. Qian, J. Wang, S. Wang*, J. Lin*, “Visible Colorimetric Dosimetry of Ultraviolet and Ionizing Radiations by a Dual-Module Photochromic Nanocluster” Nat. Commun., 2021, 12, 2798.

(39) J. Li, B. Li, N. Shen, L. Chen, Q. Guo, L. Chen, L. He, X. Dai, Z. Chai, S. Wang*. “Task-Specific Tailored Cationic Polymeric Network with High Base-Resistance for Unprecedented 99TcO4– Cleanup from Alkaline Nuclear Waste” ACS Cent. Sci., 2021, 7, 1441-1450.

(38) M. Yuan, F. Ma, X. Dai, L. Chen, F. Zhai, L. He, M. Zhang, J. Chen, J. Shu, X. Wang, Y. Zhang, X. Fu, Z. Li, C. Guo, L. Chen, Z. Chai, S. Wang*. “Deuterated Covalent Organic Framework with Significant Enhanced Luminescence” Angew. Chem. Int. Ed., 2021, 60, 20970-20976.

(37) S. Zhang, H. Li, S. Wang*, “Construction of an Ion Pathway Boosts Uranium Extraction from Seawater” Chem, 2020, 7, 1504-1505. 

(36) J. Chen, M. Zhang, J. Shu, M. Yuan, W. Yan, P. Bai, L. He, N. Shen, S. Gong, D. Zhang, J. Li, J. Hu, R. Li, G. Wu, Z. Chai, J. Yu, S. Wang*. “Electron Beam Irradiation Induced Formation of Defect‐Rich Zeolites under Ambient Condition with Minutes” Angew. Chem. Int. Ed., 2021, 60, 14858-14863.

(35) M. Zhang, C. Liang, G. Cheng, J. Chen, Y. Wang, L. He, L. Cheng, S. Gong, D. Zhang, J. Li, S. Hu*, J. Diwu, G. Wu, Y. Wang*, Z. Chai, S. Wang*. “Intrinsic Semiconducting Behavior in a Large Mixed-Valent Uranium (V/VI) Cluster”. Angew. Chem. Int. Ed., 2021, 60, 9886-9890.

(34) H. Li, S. Wang*, “Reaction: Semiconducting MOFs Offer New Strategy for Uranium Extraction from Seawater” Chem, 2021, 7, 279-280. 

(33) C. Ji, Y. Li, X. Liu, Y. Wang*, T. Zhu, Q. Chen, L. Li, S. Wang*, J. Luo*, “Monolayer-to-Multilayer Dimensionality Reconstruction in a Hybrid Perovskite for Exploring Bulk Photovoltaic Effect Enables Passive X-ray Detection” Angew. Chem. Int. Ed., 2021, 60, 20970-20976.

(32) L. He, L. Chen, X. Dong, S. Zhang, M. Zhang, X. Dai, X. Liu, P. Lin, K. Li, C. Chen, T. Pan, F. Ma, J. Chen, M. Yuan, Y. Zhang, L. Chen, R. Zhou, Y. Han*, Z. Chai, S. Wang*. “A Nitrogen-Rich Covalent Organic Framework for Simultaneous Dynamic Capture of Iodine and Methyl Iodide” Chem, 2021, 7, 699-714.

(31) N. Shen, Z. Yang, S. Liu, X. Dai, C. Xiao*, K. Taylor-Pashow, D. Li, C. Yang, J. Li, Y. Zhang, M. Zhang, R. Zhou*, Z. Chai, S. Wang*. “99TcO4- Removal from Legacy Defense Nuclear Waste by an Alkaline-Stable 2D Cationic Metal-Organic Framework” Nat. Commun., 2020, 11, 5571.

(30) L. Cheng, C. Liang; W. Liu, Y. Wang, B. Chen, H. Zhang, Y. Wang*, Z. Chai, S. Wang*. “Three-Dimensional Polycatenation of a Uranium-Based Metal-Organic Cage: Structural Complexity and Radiation Detection” J. Am. Chem. Soc., 2020, 142, 16218-16222.

(29) H. Liu, H. Qin, N. Shen, S. Yan, Y. Wang, X. Yin, X. Chen, C. Zhang, X. Dai*, R. Zhou, X. Ouyang, Z. Chai, S. Wang*. “Emergence of Radical-Stabilizing Metal-Organic Framework as a New Type of Radio-Photoluminescence Dosimeter” Angew. Chem. Int. Ed., 2020, 59, 15209-15214.

(28) C. Liang, S. Zhang, L. Cheng, J. Xie, Y. He, F. Zhai, Y. Wang*, Z. Chai, S. Wang*. “Thermoplastic Membranes Incorporating Semiconductive Metal-Organic Frameworks: an Advance on Flexible X-ray Detectors” Angew. Chem. Int. Ed., 2020, 59, 11856-11860.

(27) Y. Wang, S. Hu, L. Cheng, C. Liang, X. Yin, H. Zhang, A. Li, D. Sheng, J. Diwu, X. Wang*, J. Li*, Z. Chai, S. Wang*. “Stabilization of Plutonium(V) within a Crown Ether Inclusion Complex” CCS Chem., 2020, 2, 425-431.

(26) M. Zhang, J. Chen, S. Zhang, X. Zhou, L. He, M. V. Sheridan, M. Yuan, M. Zhang, L. Chen, X. Dai, F. Ma, J. Wang, J. Hu, G. Wu, X. Kong, R. Zhou, T. E. Albrecht-Schmitt, Z. Chai, S. Wang*. “Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions” J. Am. Chem. Soc., 2020, 142, 9169-9174.

(25) Q. Sun, L. Zhu, B. Aguila, P. K. Thallapally, C. Xu, J. Chen, S. Wang*, D. Rogers, S. Ma*, “Optimizing Radionuclide Sequestration in Anion Nanotraps with Record Pertechnetate Sorption” Nat. Commun., 2019, 10, 1646.

(24) H. Zhang, W. Liu, A. Li, D. Zhang, X. Li, F. Zhai, L. Chen, L. Chen, Y. Wang, S. Wang*. “Three Mechanisms in One Material: Uranium Capture by a Polyoxometalate-Organic Framework through Combined Complexation, Chemical Reduction, and Photocatalytic Reduction” Angew. Chem. Int. Ed., 2019, 58, 16110-16114 (VIP Paper; Highlighted in ChemistryViews).

(23) X. Wang, X. Dai, C. Shi, J. Wan, M. A. Silver, L. Zhang, L. Chen, X. Yi, B. Chen, D. Zhang, K. Yang, J. Diwu*, J. Wang, Y. Xu, R. Zhou*, Z. Chai, S. Wang*. “A 3,2-Hydroxypyridinone-based Decorporation Agent that Removes Uranium from Bones in vivo” Nat. Commun., 2019, 10, 2570 (Highlighted in ChemistryWorld).

(22) D. Gui, W. Duan, J. Shu, F. Zhai, N. Wang, X. Wang, J. Xie, H. Li, L. Chen, J. Diwu, Z. Chai, S. Wang*. “Persistent Superprotonic Conductivity in the Order of 10-1 S•cm-1 Achieved through Thermally Induced Structural Transformation of a Uranyl Coordination Polymer” CCS Chem., 2019, 1, 197-206.

(21) Y. Wang, X. Liu, X. Li, F. Zhai, S. Yan, N. Liu, Z. Chai, Y. Xu*, X. Ouyang*, S. Wang*. “Direct Radiation Detection by a Semiconductive Metal-Organic Framework” J. Am. Chem. Soc., 2019, 141, 8030-8034.

(20) J. Zhang, L. Chen, X. Dai, L. Zhu, C. Xiao, L. Xu, Z. Zhang, E. V. Alekseev, Y. Wang, C. Zhang, H. Zhang, Y. Wang, J. Diwu*, Z. Chai, S. Wang*. “Distinctive Two-Step Intercalation of Sr2+ into a Coordination Polymer with Record High 90Sr Uptake Capabilities” Chem, 2019, 5, 977-994.

(19) D. Sheng, L. Zhu, X. Dai, C. Xu, P. Li, Carolyn I. Pearce, C. Xiao*, J. Chen, R. Zhou, T. Duan, O. K. Farha, Z. Chai, S. Wang*. “Successful Decontamination of 99TcO4− in Groundwater at Legacy Nuclear Sites by a Cationic Metal-Organic Framework with Hydrophobic Pockets” Angew. Chem. Int. Ed., 2019, 58, 4968-4972.

(18) L. He, S. Liu, L. Chen, X. Dai, J. Li, M. Zhang, F. Ma, C. Zhang, Z. Yang*, R. Zhou, Z. Chai, S. Wang*. “Mechanism Unraveling for Ultrafast and Selective 99TcO4- Uptake by a Radiation-Resistant Cationic Covalent Organic Framework: A Combined Radiological Experiment and Molecular Dynamics Simulation Study” Chem. Sci., 2019, 10, 4293-4305.

(17) W. Liu, X. Dai, Y. Wang, L. Song, L. Zhang, D. Zhang, J. Xie, L. Chen, J. Diwu, J. Wang, Z. Chai, S. Wang*. “Ratiometric Monitoring of Thorium Contamination in Natural Water Using a Dual-Emission Luminescent Europium Organic Framework” Environ. Sci. Technol., 2019, 53, 332-341.

(16) J. Li, X. Dai, L. Zhu, C. Xu, D. Zhang, M. A. Silver, P. Li, L. Chen, Y. Li, D. Zuo, H. Zhang, C. Xiao*, J. Chen, J. Diwu, O. K. Farha, T. E. Albrecht-Schmitt, Z. Chai, S. Wang*. “99TcO4- Remediation by a Cationic Polymeric Network” Nat. Commun., 2018, 9, 3007.

(15) D. Gui, X. Dai, Z. Tao, T. Zheng, X. Wang, M. A. Silver, J. Shu, L. Chen, Y. Wang, T. Zhang, J. Xie, L. Zou, Y. Xia, J. Zhang, J. Zhang, L. Zhao*, J. Diwu, R. Zhou*, Z. Chai, S. Wang*. “Unique Proton Transportation Pathway in a Robust Inorganic Coordination Polymer Leading to Intrinsically High and Sustainable Anhydrous Proton Conductivity” J. Am. Chem. Soc., 2018, 140, 6146-6155.

(14) Y. Wang, W. Liu, Z. Bai, T. Zheng, M. A. Silver, Y. Li, Y. Wang, X. Wang, J. Diwu, Z. Chai, S. Wang*. “Employing a Unique Unsaturated Th4+ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation” Angew. Chem. Int. Ed., 2018, 57, 5783-5787.

(13) Y. Wang, X. Yin, W. Liu, J. Chen, M. A. Silver, D. Sheng, L. Chen, J. Diwu, N. Liu, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators” Angew. Chem. Int. Ed., 2018, 57, 7883-7887 (Selected as Journal Inside Cover Art).

(12) L. Zhu, D. Sheng, C. Xu, X. Dai, M. A. Silver, J. Li, P. Li, Y. Wang, Y. Wang, C. Xiao*, J. Chen, R. Zhou, C. Zhang, O. K. Farha, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Identifying the Recognition Site for Selective Trapping of 99TcO4- in a Hydrolytically Stable and Radiation Resistant Cationic Metal-Organic Framework” J. Am. Chem. Soc., 2017, 139, 14873-14876.

(11) Y. Li, Z. Yang, Y. Wang, Z. Bai, Z. Tao, X. Dai, S. Liu, D. Gui, W. Liu, M. Chen, L. Chen, J. Diwu, L. Zhu, R. Zhou*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “A Mesoporous Cationic Thorium-Organic Framework that Rapidly Traps Anionic Persistent Organic Pollutants” Nat. Commun., 2017, 8, 1354.

(10) L. Zhu, L. Zhang, J. Li, D. Zhang, L. Chen, D. Sheng, S. Yang, C. Xiao*, J. Wang, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Selenium Sequestration in a Cationic Layered Rare Earth Hydroxide: A Combined Batch Experiments and EXAFS Investigation” Environ. Sci. Technol., 2017, 51, 8606-8615.

(9) L. Zhu, C. Xiao, X. Dai, J. Li, D. Gui, D. Sheng, L. Chen, R. Zhou, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Exceptional Perrhenate/Pertechnetate Uptake and Subsequent Immobilization by a Low-Dimensional Cationic Coordination Polymer: Overcoming the Hofmeister Bias Selectivity” Environ. Sci. Technol. Lett., 2017, 4, 316-322.

(8) J. Xie, Y. Wang, W. Liu, X. Yin, L. Chen, Y. Zou, J. Diwu, Z. Chai, T. E. Albrecht-Schmitt, G. Liu, S. Wang*. “Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework” Angew. Chem. Int. Ed., 2017, 56, 7500-7004.

(7) W. Liu, X. Dai, Z. Bai, Y. Wang, Z. Yang, L. Zhang, L. Xu, L. Chen, Y. Li, D. Gui, J. Diwu, J. Wang, R. Zhou*, Z. Chai, S. Wang*. “Highly Sensitive and Selective Uranium Detection in Natural Water Systems Using a Luminescent Mesoporous Metal-Organic Framework Equipped with Abundant Lewis Basic Sites: a Combined Batch, X-ray Absorption Spectroscopy, and First Principle Simulation Investigation” Environ. Sci. Technol., 2017, 51, 3911-3921.

(6) Y. Wang, R. Morales-Martinenz, X. Zhang, W. Yang, Y. Wang, A. Rodriguez-Fortea*, J. M. Poblet, L. Feng*, S. Wang*, N. Chen*, “Unique Four-Electron Metal-to-Cage Transfer of Th to a C82 Fullerene Cage: Complete Structural Characterization of Th@C3V(8)-C82” J. Am. Chem. Soc., 2017, 139, 5110-5116.

(5) D. Sheng, L. Zhu, C. Xu, C. Xiao*, Y. Wang, Y. Wang, L. Chen, J. Diwu, J. Chen, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Efficient and Selective Uptake of TcO4- by a Cationic Metal-Organic Framework Material with Open Ag+ Sites” Environ. Sci. Technol., 2017, 51, 3471-3479.

(4) T. Zheng, Z. Yang, Z. Liu, D. Gui, X. Dai, S. Liu, L. Zhang, Y. Gao, L. Chen, D. Sheng, Y. Wang, J. Diwu, J. Wang, R. Zhou*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Overcoming the Crystallization and Designability Issues in the Ultrastable Zirconium Phosphonate Framework System” Nat. Commun., 2017, 8, 15369.

(3) X. Yin, Y. Wang, X. Bai, Y. Wang, L. Chen, C. Xiao, J. Diwu, S. Du*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Rare Earth Separations by Selective Borate Crystallization” Nat. Commun., 2017, 8, 14438.

(2) L. Xu, T. Zheng, S. Yang*, L. Zhang, J. Wang, W. Liu, L. Chen, J. Diwu, Z. Chai, S. Wang*. “Uptake Mechanisms of Eu(III) on Hydroxyapatite: A Potential Permeable Reactive Barrier Backfill Material for Trapping Trivalent Minor Actinides” Environ. Sci. Technol., 2016, 50, 3852-3859.

(1) Y. Wang, Z. Liu, Y. Li, Z. Bai, W. Liu, Y. Wang, X. Xu, C. Xiao, D. Sheng, J. Diwu*, J. Su*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions” J. Am. Chem. Soc., 2015, 137, 6144-6147.