Surprising Coordination for Low-Valent Actinides Resembling Uranyl(VI) in Thorium(IV) organic Hybrid Layered and Framework Structures Based on a Graphene-Like (6,3) Sheet Topology

日期:2016-4-21 13:29:12 人气:119 

Yuxiang Li,† Zhehui Weng,† Yanlong Wang,† Lanhua Chen, Daopeng Sheng, Juan Diwu, Zhifang Chai, Thomas E. Albrecht-Schmitt,and Shuao Wang,* “Surprising Coordination for Low-Valent Actinides Resembling Uranyl(VI) in Thorium(IV) Organic Hybrid Layered and Framework Structures Based on a Graphene-Like (6,3) Sheet Topology”. Dalton Trans., 2015, accept.

Abstract:

Three thorium(IV)-based metal-organic hybrid compounds with 2D layered and 3D framework structures exhibitinggraphene-like (6,3) sheet topologies were prepared with linkers with threefold symmetry. These three compounds contain rare and relatively anisotropic coordination environments for low-valent actinides that are similar to those often observed for high-valent actinide ions.

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