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第五娟


 日期:2013-4-23 11:57:02 人气:4833 

第五娟,教授、硕士生导师

电话:0512-65882579     传真:0512-65884380

电子邮箱:diwujuan@suda.edu.cn
通讯地址:苏州工业园区仁爱路199, 邮编215123

个人简历:

第五娟  苏州大学医学部放射医学与防护学院、放射医学及交叉学科研究院高聘教授,硕生生导师。2008年毕业于中国科学技术大学材料科学与工程系材料化学专业。20128月毕业于美国圣母大学锕系元素能源前沿研究中心,获博士学位,导师Prof. Thomas E. Albrecht-Schmitt20128月起在加州大学伯克利分校化学系及劳伦斯伯克利国家实验室开展博士后研究工作,合作导师 美国科学院院士Prof. Kenneth N. RaymondDr. David K. Shuh。迄今为止共发表SCI论文40余篇(其中一作及通讯作者文章15篇)。受邀为英国皇家化学会RSC出版的《Metal Phosphonate Chemistry》一书撰写第19“Structural Chemistry of Transuranium  Phosphonates”,综述了超铀元素有机磷酸盐体系的结构特点。

研究方向:

主要研究方向集中在锕系元素配位化学,并将其应用于核乏废料后处理,环境中核素迁移机制研究和体内放射性核素促排药物的研究中,具体工作内容涵盖了放射化学、核科学与技术及环境化学等多个交叉研究领域。

科研项目:

国家自然科学基金委员会面上项目,溶剂热和离子热法制备锕系元素有机膦酸盐晶体及其光谱表征(21471107),2014年 ,85万, 主持

国家自然科学基金委员会青年基金羟基吡啶酮类药物对锕系元素的广谱促排机理和效果研究,(81402628),2014年, 23万,主持

江苏省自然科学基金青年基金,2014年,离子液体中有机磷类配体对锕系元素萃取机理的配位化学研究(BK20140303)20万,主持

江苏省博士计划世界名校类, 2014年,15万,主持

代表性论著:

1.期刊论文:

(1) L. Chen, T. Zheng, S. Bao, L. Zhang, Hsin-Kuan Liu, L. Zheng, J. Wang, Y. Wang, J. Diwu*, Z. Chai, T. E. Albrecht-Schmitt, and S. Wang*, A Mixed-Valent Uranium Phosphonate Framework Containing UIV, UV, and UVI, Chem. Eur. J., 2016, 22, 1195411957.

(2) D. Gui,? T. Zheng,? L. Chen, Y. Wang, Y. Li, D. Sheng, J. Diwu,* Z. Chai, T. E. Albrecht-Schmitt, and S. Wang*, “Hydrolytically Stable Nanoporous Thorium Mixed Phosphite and Pyrophosphate Framework Generated from Redox-Active Ionothermal Reactions”,  Inorg. Chem., 2016, 55, 3721?3723.

(3) T. Zheng, Y. Gao, D. Gui, L. Chen, D. Sheng, J. Diwu*, Z. Chai, T. E Albrecht-Schmitt, and S. Wang*, “Atypical Temperature-Dependence of Symmetry Transformation Observed in a Uranyl Phosphonate” Dalton. Trans., 2016, 45, 9031-9035.

(4) T. Zheng, Y. Gao, L. Chen, Z. Liu, J. Diwu*, Z. Chai, T. E. Albrecht-Schmitt, and S. Wang*, “A new chiral uranyl phosphonate framework consisting of achiral building units generated from ionothermal reaction: structure and spectroscopy characterizations” Dalton. Trans., 2015, 44, 1815818166.

(5) Y. Wang, Z. Liu, Y. Li, Z. Bai, W. Liu, Y. Wang, X. Xu, C. Xiao, D. Sheng, J. Diwu*, J. Su*, Z. Chai, T. E. Albrecht-Schmitt, and S. Wang*, “Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can E?ectively Remove Cesium from Aqueous Solutions” J. Am. Chem. Soc., 2015, 137, 6144-6147.

(6) T. Zheng, Q. Wu, Y. Gao, D. Gui, S. Qiu, L. Chen, D. Sheng, J. Diwu*, W. Shi*, Z. Chai, T. E. Albrecht-Schmitt, and S. Wang*, “Probing the In?uence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation” Inorg. Chem., 2015, 54, 3864-3874.

(7) J. Diwu, D. J. Grant, S. Wang, L. Gagliardi, T. E. Albrecht-Schmitt, “Periodic Trends in Lanthanide and Actinide Phosphonates: Discontinuity between Plutonium and Americium” Inorg. Chem., 51, 6906-6915, 2012;

(8) J. Diwu, Thomas E. Albrecht-Schmitt*, “Mixed-Valence Uranium (IV, VI) Diphosphonates: Synthesis, Structure and Spectroscopy” Inorg. Chem., 51, 4432-4434, 2012;

(9) J. Diwu, Thomas E. Albrecht-Schmitt*, “Chiral Uranium Methylenediphosphonate Framework Structure with High Porosity that is Built from Achiral Units” Chem. Comm., 48, 3827-2829, 2012;

(10) J. Diwu, S. Wang, T. E. Albrecht-Schmitt, “Periodic Trends in Hexanuclear Clusters” Inorg. Chem., 51, 4088-4093, 2012;

(11) J. Diwu, S. Wang, J. Good, D. Victoria, T. E. Albrecht-Schmitt, “Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates” Inorg. Chem., 50, 4842-4850, 2011;

(12) J. Diwu, S. Wang, Z. Liao, P. C. Burns, T. E. Albrecht-Schmitt, “Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates” Inorg. Chem., 49, 10074-10080, 2010;

(13) J. Diwu, A. Nelson, S. Wang, T. E. Albrecht-Schmitt, “Comparisons of Pu(IV) and Ce(IV) Diphosphonates” Inorg. Chem., 49, 3337-3342, 2010;

专著:

J. Diwu and T. E. Albrecht-Schmitt, in Metal Phosphonate Chemistry, chapter 19, Chemistry of Transuranium Phosphonates (Eds: Abraham Clearfield, and Konstantinos Demadis), RSC Publishing, London, 607-631, 2011.

荣誉奖励:

1. 2014年 江苏省科协优秀青年科学工作者

2. 2014江苏省双创博士计划

课程教学及招生信息

1. 核能的历史与展望新生研讨课),共同主持

2. 苏大课程2014—3I工程全英文教学示范课程, 放射化学,主持

长期招收无机化学,环境化学及放射医学的优秀研究生及科研助理。同时欢迎化学专业及医学类本科生提前来我们课题组参加带薪科研和完成毕业论文。


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